{"id":21923,"date":"2017-12-28T01:20:00","date_gmt":"2017-12-28T00:20:00","guid":{"rendered":"https:\/\/www.sonnenseite.com\/science\/columbia-engineers-develop-floating-solar-fuels-rig-for-seawater-electrolysis.html"},"modified":"2017-12-28T01:20:00","modified_gmt":"2017-12-28T00:20:00","slug":"columbia-engineers-develop-floating-solar-fuels-rig-for-seawater-electrolysis","status":"publish","type":"post","link":"https:\/\/www.sonnenseite.com\/en\/science\/columbia-engineers-develop-floating-solar-fuels-rig-for-seawater-electrolysis\/","title":{"rendered":"Columbia Engineers Develop Floating Solar Fuels Rig for Seawater Electrolysis"},"content":{"rendered":"<p>Design is the first practical floating solar hydrogen-generating device to perform water electrolysis without pumps or membranes; could lead to low-cost, sustainable hydrogen production.<\/p>\n<p> <!--more--> <\/p>\n<p>&nbsp; In a single hour, more energy from the sun hits the Earth than all the  energy used by humankind in an entire year. Imagine if the sun&rsquo;s energy  could be harnessed to power energy needs on Earth, and done in a way  that is economical, scalable, and environmentally responsible.  Researchers have long seen this as one of the grand challenges of the 21<sup>st<\/sup> century.<\/p>\n<p> \t<a href=\"http:\/\/cheme.columbia.edu\/daniel-esposito\">Daniel Esposito<\/a>, assistant professor of <a href=\"http:\/\/cheme.columbia.edu\/\">chemical engineering<\/a>&nbsp;at <a href=\"http:\/\/engineering.columbia.edu\/\">Columbia Engineering<\/a>, has been studying water electrolysis&mdash;the splitting of water into oxygen (O<span>2<\/span>) and hydrogen (H<span>2<\/span>)  fuel&mdash;as a way to convert electricity from solar photovoltaics (PVs)  into storable hydrogen fuel. Hydrogen is a clean fuel that is currently  used to propel rockets in NASA&rsquo;s space program and is widely expected to  play an important role in a sustainable energy future. The vast  majority of today&rsquo;s hydrogen is produced from natural gas through a  process called steam methane reforming that simultaneously releases CO<span>2<\/span>, but water electrolysis using electricity from solar PV offers a promising route to produce H<span>2<\/span> without any associated CO<span>2<\/span> emissions.<\/p>\n<p> \tEsposito&rsquo;s team has now developed a novel photovoltaic-powered  electrolysis device that can operate as a stand-alone platform that  floats on open water. His floating PV-electrolyzer can be thought of as a  &ldquo;solar fuels rig&rdquo; that bears some resemblance to deep-sea oil rigs,  except that it would produce hydrogen fuel from sunlight and water  instead of extracting petroleum from beneath the sea floor. The <a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S036031991734466X\">study<\/a> (DOI: 10.1016\/j.ijhydene.2017.11.086), &ldquo;<em>Floating Membraneless PV-Electrolyzer Based on Buoyancy-Driven Product Separation<\/em>,&rdquo; was published today by <a href=\"https:\/\/www.journals.elsevier.com\/international-journal-of-hydrogen-energy\"><em>International Journal of Hydrogen Energy<\/em><\/a>.<\/p>\n<p>&nbsp;<\/p>\n<p><iframe loading=\"lazy\" frameborder=\"0\" src=\"http:\/\/www.youtube.com\/embed\/Us40HQJ_HoA\" height=\"360\" width=\"100%\"><\/iframe><\/p>\n<p>The researchers&rsquo; key innovation is the method by which they separate the H<span>2<\/span> and O<span>2<\/span>  gases produced by water electrolysis. State-of-the-art electrolyzers  use expensive membranes to maintain separation of these two gases. The  Columbia Engineering device relies instead on a novel electrode  configuration that allows the gases to be separated and collected using  the buoyancy of bubbles in water. The design enables efficient operation  with high product purity and without actively pumping the electrolyte.  Based on the concept of buoyancy-induced separation, the simple  electrolyzer architecture produces H<span>2<\/span> with purity as high as 99 percent.<\/p>\n<p>&nbsp; &ldquo;The simplicity of our PV-electrolyzer architecture&mdash;without a membrane  or pumps&mdash;makes our design particularly attractive for its application to  seawater electrolysis, thanks to its potential for low cost and higher  durability compared to current devices that contain membranes,&rdquo; says  Esposito, whose <a href=\"https:\/\/solarfuelsengineering.com\/\">Solar Fuels Engineering Laboratory<\/a>&nbsp;develops  solar and electrochemical technologies that convert renewable and  abundant solar energy into storable chemical fuels. &ldquo;We believe that our  prototype is the first demonstration of a practical membraneless  floating PV-electrolyzer system, and could inspire large-scale &lsquo;solar  fuels rigs&rsquo; that could generate large quantities of H<span>2<\/span>  fuel from abundant sunlight and seawater without taking up any space on  land or competing with fresh water for agricultural uses.&rdquo;<\/p>\n<p> \tCommercial electrolyzer devices rely on a membrane, or divider, to separate the electrodes within the device from which H<span>2<\/span> and O<span>2<\/span>  gas are produced. Most of the research for electrolysis devices has  been focused on devices that incorporate a membrane. These membranes and  dividers are prone to degradation and failure and require a high purity  water source. Seawater contains impurities and microorganisms that can  easily destroy these membranes.<\/p>\n<p> \t&ldquo;Being able to safely demonstrate a device that can perform  electrolysis without a membrane brings us another step closer to making  seawater electrolysis possible,&rdquo; says Jack Davis, the paper&rsquo;s first  author and a PhD student working with Esposito. &ldquo;These solar fuels  generators are essentially artificial photosynthesis systems, doing the  same thing that plants do with photosynthesis, so our device may open up  all kinds of opportunities to generate clean, renewable energy.&rdquo;<\/p>\n<p> \tCrucial to the operation of Esposito&rsquo;s PV-electrolyzer is a novel  electrode configuration comprising mesh flow-through electrodes that are  coated with a catalyst only on one side. These asymmetric electrodes  promote the evolution of gaseous H<span>2<\/span> and O<span>2<\/span> products on only the outer surfaces of the electrodes where the catalysts have been deposited. When the growing H<span>2<\/span> and O<span>2<\/span>  bubbles become large enough, their buoyancy causes them to detach from  the electrode surfaces and float upwards into separate overhead  collection chambers.<\/p>\n<p> \tThe team used the Columbia Clean Room to deposit platinum  electrocatalyst onto the mesh electrodes and the 3D-printers in the  Columbia Makerspace to make many of the reactor components. They also  used a high-speed video camera to monitor transport of H<span>2<\/span> and O<span>2<\/span>  bubbles between electrodes, a process known as &ldquo;crossover.&rdquo; Crossover  between electrodes is undesirable because it decreases product purity,  leading to safety concerns and the need for downstream separation units  that make the process more expensive.<\/p>\n<p> \tIn order to monitor H<span>2<\/span> and O<span>2<\/span>  crossover events, the researchers incorporated windows in all of their  electrolysis devices so that they could take high-speed videos of gas  bubble evolution from the electrodes while the device was operating.  These videos were typically taken at a rate of 500 frames per second (a  typical iPhone captures video at a rate of 30 frames per second).<\/p>\n<p> \tThe team is refining their design for more efficient operation in real  seawater, which poses additional challenges compared to the more ideal  aqueous electrolytes used in their laboratory studies. They also plan to  develop modular designs that they can use to build larger, scaled-up  systems.<\/p>\n<p> \tEsposito adds: &ldquo;There are many possible technological solutions to  achieve a sustainable energy future, but nobody knows exactly what  specific technology or combination of technologies will be the best to  pursue. We are especially excited about the potential of solar fuels  technologies because of the tremendous amount of solar energy that is  available. Our challenge is to find scalable and economical technologies  that convert sunlight into a useful form of energy that can also be  stored for times when the sun is not shining.&rdquo;<\/p>\n<p>&nbsp;<\/p>\n<h5 class=\"green\">Source<\/h5>\n<p><a href=\"http:\/\/engineering.columbia.edu\/news\/daniel-esposito-solar-fuels-seawater-electrolysis\" target=\"_blank\" rel=\"noopener noreferrer\">COLUMBIA | ENGINEERING |&nbsp;by Holly Evarts 2017<\/a><\/p>\n<div class=\"shariff shariff-align-flex-start shariff-widget-align-flex-start\"><div class=\"ShariffHeadline\">Diese Meldung teilen<\/div><ul class=\"shariff-buttons theme-round orientation-horizontal buttonsize-medium\"><li class=\"shariff-button facebook shariff-nocustomcolor\" style=\"background-color:#4273c8;border-radius:1%\"><a href=\"https:\/\/www.facebook.com\/sharer\/sharer.php?u=https%3A%2F%2Fwww.sonnenseite.com%2Fen%2Fscience%2Fcolumbia-engineers-develop-floating-solar-fuels-rig-for-seawater-electrolysis%2F\" title=\"Bei Facebook teilen\" aria-label=\"Bei Facebook teilen\" role=\"button\" rel=\"nofollow\" class=\"shariff-link\" style=\";border-radius:1%; 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Photovoltaic cells positioned on top of the &ldquo;mini rig&rdquo; convert light into electricity that is used to power the membraneless electrolyzer submerged below. The generated H2 bubbles are harvested within the interior of the device as they float upwards, while O2 bubbles are allowed to vent to the atmosphere. 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